2-Nitrobenzyl Isocyanide as a Universal Convertible Isocyanide
نویسندگان
چکیده
منابع مشابه
A Universal Isocyanide for Diverse Heterocycle Syntheses
Novel scaffolds are of uttermost importance for the discovery of functional material. Three different heterocyclic scaffolds easily accessible from isocyanoacetaldehyde dimethylacetal 1 by multicomponent reaction (MCR) are described. They can be efficiently synthesized by a Ugi tetrazole multicomponent reaction of 1. We discuss the synthesis, 3D structures, and other physicochemical properties.
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The title compound, [Ni(C(5)H(9)N)(3)(CO)], was prepared from Ni(CO)(4) and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent mol-ecules per asymmetric unit. The central Ni atom of each independent mol-ecule has a nearly perfect tetra-hedral coordination environment, comprising one carbon monoxide and three isocyanide ligands. The title compound is the fir...
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Bis(p-tolylsulfonylmethylisocyanide)silver nitrate is obtained from the reaction of the isocyanide ligand with silver nitrate in chloroform regardless of the applied ratio of the reactands (1:1 or 2:1). The crystal structure of the product has been determined. In the complex molecule with C2 symmetry, the nitrate anion is attached to the silver center as an η2-chelating ligand. Owing to this ap...
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ژورنال
عنوان ژورنال: Asian Journal of Organic Chemistry
سال: 2017
ISSN: 2193-5807
DOI: 10.1002/ajoc.201700177